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Talk:Chromium(II) acetate - Wikipedia, the free encyclopedia

Talk:Chromium(II) acetate

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Chemicals WikiProject Chromium(II) acetate is within the scope of WikiProject Chemicals, which aims to improve Wikipedia's coverage of chemicals. To participate, help improve this article or visit the project page for details on the project.
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Is chromium (II) acetate soluble in water at STP? -- VGF11 00:36, 6 December 2006 (UTC)

[edit] Structure

Hi all,

I generated a fake structure for this molecule by getting the X-ray diffraction data for a similar compound from

Cotton, F.A. and Hillard, E.A. and Murillo, C.A. and Zhou, H.-C. (2000). "After 155 Years, A Crystalline Chromium Carboxylate with a Supershort Cr-Cr Bond". Journal of the American Chemical Society 122 (2): 416-417. ,

with the relevant data at ACS Supporting Information, hacking together a molfile, and editing it in pymol. It's not strictly accurate: it looks to me as if the bond lengths from the Cr to the H2O are wrong, and for some reason the angles from the Chromium atoms to the acetates aren't 90° like in the X-ray diffraction drawing. I put my molfile in the image page, so if you can do better given the data, go for it!--Slashme 22:21, 27 October 2007 (UTC)

Nice job, but the previously displayed picture is superior, I thought. If you are looking for structures to draw, ZrCl4 is wanting, and the same pic could be used for many related cmpds.--Smokefoot 02:43, 28 October 2007 (UTC)

Wow, I just went to figure out what that would look like, and I see it's just been done! --Slashme 20:17, 28 October 2007 (UTC)

Previously displayed picture? What previously displayed picture? There wasn't one when I got here. --Slashme 09:11, 28 October 2007 (UTC)
This one, a couple of edits ago:
The molecular structure of hydrated chromium(II) acetate, Cr2(CH3CO2)4(H2O)2.
The molecular structure of hydrated chromium(II) acetate, Cr2(CH3CO2)4(H2O)2.
Oh, OK, I never noticed that. Why was it removed? --Slashme 18:40, 28 October 2007 (UTC) I see, new chembox, baby with bathwater. I've put back the picture. --Slashme 20:23, 28 October 2007 (UTC)


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