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Beryllium iodide - Wikipedia, the free encyclopedia

Beryllium iodide

From Wikipedia, the free encyclopedia

Beryllium iodide
Systematic name Beryllium iodide
Identifiers
CAS number [7787-53-3]
Properties
Molecular formula BeI2
Molar mass 262.821 g/mol
Appearance colorless needle-like crystals
Density 4.325 g/cm³
Melting point

510°C

Boiling point

590°C[1]

Solubility in water Reacts violently with water[1]
Solubility Slightly soluble in CS2
Soluble in ethanol[2]
Hazards
Main hazards see Berylliosis
Related compounds
Other anions Beryllium fluoride
Beryllium chloride
Beryllium bromide
Other cations Magnesium iodide
Calcium iodide
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Beryllium iodide is the chemical compound with the formula BeI2. It is very hygroscopic and reacts violently with water, forming hydroiodic acid.

[edit] Reactions

Beryllium iodide can be prepared by reacting beryllium metal with elemental iodine at temperatures of 500°C to 700°C[1]:

Be + I2 → BeI2

Beryllium iodide is also formed when beryllium carbide with hydrogen iodide in the gas phase:

Be2C + 4 HI → 2 BeI2 + CH4

The iodine in beryllium iodide is easily replaced with the other halogens; it reacts with fluorine giving beryllium fluoride and fluorides of iodine, with chlorine giving beryllium fluoride, and with bromine giving beryllium bromide. The solid and vapor are both flammable in air[2].

[edit] References

  1. ^ a b c Perry, Dale L. & Phillips, Sidney L., Handbook of Inorganic Compounds, CRC Press, pp. 63, ISBN 0849386713, <http://books.google.com/books?id=0fT4wfhF1AsC&printsec=frontcover&dq=%22beryllium+iodide%22+properties&as_brr=3#PPA63,M1>. Retrieved on 2007-12-10 
  2. ^ a b Parsons, Charles Lathrop, written at Easton, Pa., The Chemistry and Literature of Beryllium, Chemical Publishing, pp. 22-23, <http://books.google.com/books?id=7MxAAAAAIAAJ&pg=PA21&dq=%22beryllium+iodide%22&as_brr=3#PPA22,>. Retrieved on 2007-12-10 
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