Arsenic pentoxide
From Wikipedia, the free encyclopedia
Arsenic pentoxide | |
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Other names | Arsenic(V) oxide Arsenic oxide Arsenic anhydride |
Identifiers | |
CAS number | [1303-28-2] |
EINECS number | |
Properties | |
Molecular formula | As2O5 |
Molar mass | 229.8 g/mol |
Appearance | white hygroscopic powder |
Density | 4.3 g/cm3, solid |
Melting point |
315 °C (decomposes) |
Hazards | |
EU classification | Very toxic (T+) Carc. Cat. 1 Dangerous for the environment (N) |
NFPA 704 | |
R-phrases | R45, R23/25, R50/53 |
S-phrases | S53, S45, S60, S61 |
Related compounds | |
Other cations | Phosphorus pentoxide Antimony pentoxide |
Related compounds | Arsenic trioxide Arsenic acid |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
Arsenic pentoxide, As2O5, is an important commercial compound of arsenic. Its usage with respect to arsenic chemistry, as well as its toxicology are similar to arsenic trioxide, As2O3.
Contents |
[edit] Synthesis
Arsenic pentoxide can be synthesized either by burning elemental arsenic in surplus of oxygen, or by oxidizing arsenic trioxide with oxidizing agents such as ozone, hydrogen peroxide and nitric acid.[citation needed]
[edit] Reactions
Arsenic pentoxide decomposes to oxygen and As2O3 upon heating.[1] As2O5 dissolves readily in water to form arsenic acid, H3AsO4.[2]
[edit] Bibliography
Arsenic: Medical and Biological Effects of Environmental Pollutants (1977)
[edit] References
- ^ Martin Jansen (1977). "Crystal Structure of As2O5". Angewandte Chemie International Edition in English 16 (5): 314–315. doi: .
- ^ Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements, 2nd Edition, Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4. pp. 576-577
[edit] External links
- International Chemical Safety Card 0377
- NIOSH Pocket Guide to Chemical Hazards
- IARC Monograph – Arsenic and Arsenic Compounds
- NTP Report on Carcinogens – Inorganic Arsenic Compounds
- European Chemicals Bureau
- Institut national de recherche et de sécurité (1992). "Arsenic et composés minéraux."PDF Fiche toxicologique n° 192. Paris:INRS. (French)
- NIST Chemistry WebBook