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氧化亚铜 - Wikipedia

氧化亚铜

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氧化亚铜
IUPAC英文名 Copper(I) oxide
其它名稱 氧化铜(I)
識別
CAS號 1317-39-1
RTECS號 GL8050000
性質
化學式 Cu2O
摩爾質量 143.09 g mol-1
外觀 红棕色固体
密度 6.0
熔點 1235 °C (1508 K)
中的溶解度 难溶
結構
晶體結構 立方晶系
危險性
MSDS ScienceLab.com
相關化學品
其他陰離子 硫化亚铜
硫化铜
硒化亚铜
其他陽離子 氧化铜,
氧化银,
氧化镍,
氧化锌
若非注明,所有数据都依從国际单位制,以及来自标准状况(25 °C, 100 kPa)的条件。
化學品框的說明和參考文獻

氧化亞銅是一价氧化物,分子式為Cu2O。它不溶於水及有機溶劑,但可溶於濃溶液形成無色配合物 Cu(NH3)2+,其在空氣中被氧化為藍色的 [Cu(NH3)4(H2O)2]2+

氧化亞銅可溶於鹽酸生成 HCuCl2氯化亞銅的配合物),也可溶於硫酸硝酸分別形成硫酸銅硝酸銅

目录

[编辑] 半導體應用

[编辑] 參見

[编辑] 參考

  1. N. N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.
  2. Handbook of Chemistry and Physics, 71st edition, CRC Press, Ann Arbor, Michigan, 1990.
  3. The Merck Index, 7th edition, Merck & Co, Rahway, New Jersey, USA, 1960.
  4. D. Nicholls, Complexes and First-Row Transition Elements, Macmillan Press, London, 1973.
  5. P.W. Baumeister: Optical Absorption of Cuprous Oxide, Phys. Rev. 121 (1961), 359.
  6. L. Brillouin: Wave Propagation and Group Velocity, Academic Press, New York, 1960.
  7. D. Fröhlich, A. Kulik, B. Uebbing, and A. Mysyrovicz: Coherent Propagation and Quantum Beats of Quadrupole Polaritons in Cu2O, Phys. Rev. Lett. 67 (1991), 2343.
  8. L. Hanke: Transformation von Licht in Wärme in Kristallen - Lineare Absorption in Cu2O, ISBN 3-8265-7269-6, Shaker, Aachen, 2000; (Transformation of light into heat in crystals - Linear absorption in Cu2O).
  9. L. Hanke, D. Fröhlich, A.L. Ivanov, P.B. Littlewood, and H. Stolz: LA-Phonoritons in Cu2O, Phys. Rev. Lett. 83 (1999), 4365.
  10. L. Hanke, D. Fröhlich, and H. Stolz: Direct observation of longitudinal acoustic phonon absorption to the 1S-exciton in Cu2O, Sol. Stat. Comm. 112 (1999), 455.
  11. J.J. Hopfield, Theory of the Contribution of Excitons to the Complex Dielectric Constant of Crystals, Phys. Rev. 112 (1958), 1555.
  12. J.P. Wolfe and A. Mysyrowicz: Excitonic Matter, Scientific American 250 (1984), No. 3, 98.

[编辑] 外部連結


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